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Preheat oven to 350 degrees F. Line 9-in. square pan with parchment paper, leaving some overhang for easy removal.
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In large mixing bowl, whisk together cooled butternut squash purée, melted coconut oil, brown sugar, eggs and vanilla until smooth.
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In medium bowl, whisk together flour, cacao powder, baking powder, salt and instant coffee (if using).
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Add dry ingredients to wet mixture and stir gently until just combined.
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Fold in 1/2 cup chocolate chips.
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Spread batter evenly into prepared pan and sprinkle remaining 1/4 cup chocolate chips on top.
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Bake for 22–25 minutes, or until edges are set and toothpick comes out with moist crumbs.
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Cool in pan for 15 minutes. Slice once fully cooled.