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Preheat oven to 350 degrees F. Line two 9x13-inch trays with silicone mats.
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Add pecans to small bowl and toss with maple syrup. Arrange on prepared tray. Roast for 12-14 minutes, stirring periodically, until caramelized and fragrant. Set aside to cool.
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Combine sugar, butter, water, corn syrup and salt in large, heavy-bottomed stock pot. Bring to boil over medium heat, stirring until butter melts and sugar dissolves. Brush sides of pan with wet pastry brush.
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Reduce heat to low. Cook uncovered, stirring just once halfway through, until mixture reaches 290 degrees F on candy thermometer, about 15 minutes.
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Remove from heat. Pour onto second prepared tray. Cool 5 minutes.
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Scatter toffee with grated chocolate. Allow chocolate to melt 2 minutes, then spread with rubber spatula. Press maple-glazed pecans into melted chocolate.
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Refrigerate until chocolate sets. Break toffee into pieces. Store in airtight container in cool, dry place for up to 1 week.