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Place 3/4 cup warm water, yeast and sugar in a small bowl; let sit for 5 minutes until bubbly. Prep dough ingredients.
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Using stand mixer, combine flour, xanthan gum, baking powder and salt. Whisk together. Add yeast mixture, eggs and oil. Mix on medium speed with dough hook. Add 1/4 cup water, 1 tablespoon at a time, until dough is sticky but touchable. Knead in mixer for 5 minutes.
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In medium bowl with lid, combine cinnamon and sugar. Scoop tablespoon-sized dough balls and drop into cinnamon sugar. Cover and shake to coat.
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Place dough balls into greased 12-cup Bundt pan, evenly distributing. Pour remaining cinnamon sugar over top, cover and let rise in warm place until doubled, about 1 hour.
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Preheat oven to 350 degrees F. Pour melted butter over risen dough, place pan on sheet pan to catch any drips and bake for 30-40 minutes until golden brown and set. Let cool for 3 minutes before turning out onto platter.