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Preheat oven to 350 degrees F. Coat 8” cast iron skillet with butter or coconut oil.
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In small saucepan, heat butter, 1/2 cup chocolate chips and cacao powder, stirring occasionally, until melted and smooth.
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In large mixing bowl, beat eggs and coconut sugar on high speed 3 to 5 minutes, until mixture is light in color.
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In small amounts, slowly beat in melted chocolate mixture until combined.
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In separate bowl, stir together almond meal flour, coconut sugar, arrowroot powder and salt.
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Gently fold dry ingredients into wet ingredients until well combined, taking care not to overmix.
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Pour brownie batter into prepared skillet. Top with remaining chocolate chips.
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Bake 16 to 20 minutes, until sides begin to pull away from skillet and center is solid.
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Remove from oven; let cool 20 minutes.