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Split vanilla beans and scrape out pods. In pot, combine pods, seeds, sugar, syrup, chia seeds, almond milk, cocoa powder, cinnamon, cayenne pepper and salt. Simmer mixture and cover.
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Remove pot from heat and steep for 30 minutes.
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Remove vanilla pods from pot and transfer mixture to blender. Blend on high, while slowly adding guar gum.
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Refrigerate until cool.
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In blender or food processor, combine frozen bananas and cooled Mexican hot chocolate mixture until smooth and creamy. Tip: You may need to scrape down the sides of blender or food processor a few times to ensure everything is well combined.
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Add white chocolate, chili flakes, salt and cacao nibs and pulse a few times
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Transfer nice cream to a container and freeze until firm (about 2-4 hours) before serving.